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Properties of substance:
tantalum(V) chloride
Group of substances:
inorganic
Physical appearance:
monoclinic crystals
Empirical formula (Hill's system for organic substances):
Cl
5
Ta
Structural formula as text:
TaCl5
Molar/atomic mass: 358.21
Melting point (°C):
216.5
Boiling point (°C):
236
Solubility (g/100 g of solvent):
acetone
: soluble [
Ref.
]
benzene
: sparingly soluble [
Ref.
]
bromoethane
: 7.66 (0°C) [
Ref.
]
bromoethane
: 12 (20°C) [
Ref.
]
carbon disulphide
: 1.017 (0°C) [
Ref.
]
carbon disulphide
: 2.09 (14°C) [
Ref.
]
carbon disulphide
: 2.47 (20°C) [
Ref.
]
carbon disulphide
: 2.96 (25°C) [
Ref.
]
carbon tetrachloride
: 0.245 (20°C) [
Ref.
]
carbon tetrachloride
: 0.92 (30°C) [
Ref.
]
chloroform
: 3.9 (0°C) [
Ref.
]
chloroform
: 3.86 (20°C) [
Ref.
]
diethyl ether
: sparingly soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
ethylenediamine
: 1.48 (20°C) [
Ref.
]
nitrobenzene
: 4.65 (20°C) [
Ref.
]
nitrobenzene
: 4.74 (40°C) [
Ref.
]
water
: reaction [
Ref.
]
Hygroscopic:
yes
Density:
3.68 (27°C, g/cm
3
)
Vapour pressure (Torr):
1 (117.6°C)
10 (150.5°C)
100 (190.4°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-857.9 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-750.5 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
238 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
146 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
34
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
56.1
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-762 (g)
LD
50
(mg/kg):
1900 (rats, oral)
References:
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 103 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 957 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru