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Properties of substance:
phenanthrene
skc-file
Group of substances:
organic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
C
1
4
H
1
0
Molar/atomic mass: 178.24
Melting point (°C):
101
Boiling point (°C):
340.1
CAS №: 85-01-8
Solubility (g/100 g of solvent):
acetic acid
: 9.06 (23°C) [
Ref.
]
acetone
: 25.5 (0°C) [
Ref.
]
acetone
: 51.94 (20°C) [
Ref.
]
benzene
: 29.86 (5°C) [
Ref.
]
benzene
: 51.7 (20°C) [
Ref.
]
benzene
: 69.68 (30°C) [
Ref.
]
benzine: 4.53 (15.5°C) [
Ref.
]
benzine: 6.3 (30°C) [
Ref.
]
butyric acid
: 18.5 (23°C) [
Ref.
]
butyric acid
: 26.6 (39°C) [
Ref.
]
carbon disulphide
: 45.88 (5°C) [
Ref.
]
carbon disulphide
: 72.08 (20°C) [
Ref.
]
carbon disulphide
: 89.82 (30°C) [
Ref.
]
carbon tetrachloride
: 7.6 (0°C) [
Ref.
]
carbon tetrachloride
: 12.66 (10°C) [
Ref.
]
carbon tetrachloride
: 19 (20°C) [
Ref.
]
carbon tetrachloride
: 26.2 (30°C) [
Ref.
]
chloroform
: 25.5 (0°C) [
Ref.
]
chloroform
: 46.6 (20°C) [
Ref.
]
chloroform
: 64.2 (30°C) [
Ref.
]
cyclohexane
: 7.18 (20.7°C) [
Ref.
]
diethyl ether
: 8.93 (15°C) [
Ref.
]
ethanol
: 2 (14°C) [
Ref.
]
ethanol
: 4.91 (25°C) [
Ref.
]
ethanol
: 10 (78°C) [
Ref.
]
ethanol abs.
: 4.15 (20°C) [
Ref.
]
formic acid 95%
: 0.46 (20.8°C) [
Ref.
]
hexane
: 9.15 (25°C) [
Ref.
]
isobutyric acid
: 14 (23°C) [
Ref.
]
methanol
: 1.2 (0°C) [
Ref.
]
methanol
: 3.18 (20°C) [
Ref.
]
methanol
: 4.8 (30°C) [
Ref.
]
propionic acid
: 20.5 (23°C) [
Ref.
]
sulfur dioxide
: 29.9 (20°C) [
Ref.
]
toluene
: 13.8 (15.5°C) [
Ref.
]
valeric acid
: 19.9 (39°C) [
Ref.
]
water
: 0.0001 (25°C) [
Ref.
]
water
: 0.000148 (30.3°C) [
Ref.
]
water
: 0.0001845 (34.53°C) [
Ref.
]
water
: 0.00152 (73.4°C) [
Ref.
]
Density:
0.98 (4°C, g/cm
3
)
1.063 (100°C, g/cm
3
)
Refractive index (n
D
):
1.59427 (20°C)
Retention indices for gas chromatography:
1789,2 (phase - DB-5, temperature-programmed conditions, 6 K/min)
Dipole moment (D):
0 (20°C)
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
52.97
Heat of combustion (kJ/mol):
7081.4
LD
50
(mg/kg):
1800-2000 (rats, oral)
References:
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 742-744
Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 948-948
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 989-991
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.1. - Л.: Химия, 1976. - pp. 136-137 [Russian]
Другов Ю.С., Родин А.А. Мониторинг органических загрязнений природной среды. - СПб.: Наука, 2004. - pp. 129, 708 [Russian]
Клар Э. Полициклические углеводороды. - Т.1. - М.: Химия, 1971. - pp. 220-232 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 187 [Russian]
Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 975, 1036-1037, 1049-1050, 1095, 1114, 1148, 1193-1194, 1242, 1281, 1348, 1441, 1465, 1564-1565 [Russian]
Токсикологический вестник. - 2001. - №5. - pp. 35-36 [Russian]
Химическая энциклопедия. - Т. 5. - М.: Советская энциклопедия, 1999. - pp. 62-63 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru