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Properties of substance:
3-methylbutanoic acid
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
5
H
1
0
O
2
Structural formula as text:
(CH3)2CHCH2COOH
Molar/atomic mass: 102.132
Melting point (°C):
-37.6
Boiling point (°C):
176.7
CAS №: 503-74-2
Solubility (g/100 g of solvent):
chloroform
: very soluble [
Ref.
]
diethyl ether
: very soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
water
: 4.3 (20°C) [
Ref.
]
Density:
0.917 (20°C, g/cm
3
)
Dissociation:
pK
a
(1) = 4.78 (25°C, water)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-561.6 (l)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-510 (g)
LD
50
(mg/kg):
1037 (rats, oral)
1375 (mice, oral)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-29
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 303-306
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 169
Маркман А.Л. Химия липидов. - Вып. 1: Жирные кислоты. - Ташкент: Издательство АН Узбекской ССР, 1963. - pp. 134-135 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 676-677 [Russian]
Справочник химика. - Т. 3. - М.-Л.: Химия, 1965. - pp. 88 [Russian]
Токсикологический вестник. - 2001. - №6. - pp. 38-39 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru