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Properties of substance:
lithium perchlorate
Group of substances:
inorganic
Physical appearance:
colorless crystals
Empirical formula (Hill's system for organic substances):
ClLiO
4
Structural formula as text:
LiClO4
Molar/atomic mass: 106.39
Melting point (°C):
236
Decomposition temperature (°C):
350-450
Solubility (g/100 g of solvent):
1-butanol
: 79.31 (25°C) [
Ref.
]
1-propanol
: 105 (25°C) [
Ref.
]
acetone
: 137 (25°C) [
Ref.
]
diethyl ether
: 113.72 (25°C) [
Ref.
]
ethanol
: 151.76 (25°C) [
Ref.
]
ethyl acetate
: 95.12 (25°C) [
Ref.
]
i-butanol
: 58.05 (25°C) [
Ref.
]
methanol
: 182.25 (25°C) [
Ref.
]
perchloric acid anhydrous
: 0.106 (0°C) [
Ref.
]
water
: 42.7 (0°C) [
Ref.
]
water
: 49 (10°C) [
Ref.
]
water
: 56.1 (20°C) [
Ref.
]
water
: 60 (25°C) [
Ref.
]
water
: 63.6 (30°C) [
Ref.
]
water
: 72.4 (40°C) [
Ref.
]
water
: 123 (80°C) [
Ref.
]
water
: 300 (120°C) [
Ref.
]
Hygroscopic:
yes
Density:
2.43 (20°C, g/cm
3
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-381 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-254 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
125.5 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
105 (s)
Enthalpy (heat) of fusion Δ
fus
H (kJ/mol)
20.04 (s) [
Ref.
]
References:
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 4-72
Journal of the American Chemical Society. - 1923. - Vol. 45, No. 2. - pp. 296
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 921
Иванов В.М., Семененко К.А., Прохорова Г.В., Симонов Е.Ф. Натрий. - М.: Наука, 1986. - pp. 19 [Russian]
Карапетян Ю.А., Эйчис В.Н. Физико-химические свойства электролитных неводных растворов. - М.: Химия, 1989. - pp. 82-87 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 264 [Russian]
Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 238-239 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 77 [Russian]
Редкие и рассеянные элементы. Химия и технология. - Кн. 1. - М.: Мисис, 1996. - pp. 33 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 644 [Russian]
Справочник химика. - Т. 3. - М.-Л.: Химия, 1965. - pp. 301 [Russian]
Химическая энциклопедия. - Т. 2. - М.: Советская энциклопедия, 1990. - pp. 608 [Russian]
Якименко Л.М. Производство хлора, каустической соды и неорганических хлорпродуктов. - М.: Химия, 1974. - pp. 432-434, 454-455 [Russian]
Якименко Л.М., Серышев Г.А. Электрохимический синтез неорганических соединений. - М.: Химия, 1984. - pp. 79-81 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru