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Properties of substance:
trinitromethane
skc-file
Group of substances:
organic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
CHN
3
O
6
Structural formula as text:
HC(NO2)3
Molar/atomic mass: 151.04
Melting point (°C):
26.38
Decomposition temperature (°C):
100
Solubility (g/100 g of solvent):
acetone
: very soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
water
: 42 (20°C) [
Ref.
]
Numerical data:
Year of discovery: 1857
Not numerical data:
hygroscopic
volatile in steam
Density:
1.5967 (25°C, g/cm
3
)
Refractive index (n
D
):
1.4451 (24°C)
Vapour pressure (Torr):
22 (45°C)
Dipole moment (D):
2.7
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-32.8 (l)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-13.4 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
435.6 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
134.1 (g)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-19
Urbanski T. Chemistry and technology of explosives. - vol.1. - Warszawa, 1964. - pp. 587-588
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.2. - Л.: Химия, 1976. - pp. 213 [Russian]
Краткая химическая энциклопедия. - Т. 3: Мальтаза-Пиролиз. - М.: Советская энциклопедия, 1964. - pp. 549 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 565 [Russian]
Орлова Е.Ю. Химия и технология бризантных взрывчатых веществ. - Л.: Химия, 1981. - pp. 191-195 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 168 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 593 [Russian]
Энергетические конденсированные системы. - Под ред. Жукова Б.П., 2-е изд. - М.: Янус-К, 2000. - pp. 549-550 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru