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Properties of substance:
arsenic(III) oxide
Synonyms:
claudetite
Group of substances:
inorganic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
As
2
O
3
Structural formula as text:
As2O3
Molar/atomic mass: 197.84
Melting point (°C):
314
Boiling point (°C):
461
Solubility (g/100 g of solvent):
water
: 1.2 (2°C) [
Ref.
]
water
: 11.5 (100°C) [
Ref.
]
Density:
4.15 (20°C, g/cm
3
)
Vapour pressure (Torr):
10 (260°C)
100 (333°C)
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
56.1
Standard molar enthalpy (heat) of formation Δ
f
H (298 K, kJ/mol)
-654.796 (s) [for As2O3 monoclinic] [
Ref.
]
Standard molar Gibbs energy of formation Δ
f
G (298 K, kJ/mol)
-576.641 (s) [for As2O3 monoclinic] [
Ref.
]
Standard molar entropy S (298 K, J/(mol·K))
117.001 (s) [for As2O3 monoclinic] [
Ref.
]
Molar heat capacity at constant pressure C
p
(298 K, J/(mol·K))
96.979 (s) [for As2O3 monoclinic] [
Ref.
]
Enthalpy (heat) of fusion Δ
fus
H (kJ/mol)
18 (s) [
Ref.
]
References:
Dean J.A. Lange's handbook of chemistry. - 1999. - pp. 3.18
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 303-304
Ефимов А.И. и др. Свойства неорганических соединений. Справочник. - Л.: Химия, 1983. - pp. 160-161 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 82 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru