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Properties of substance:
pentaerythritol tetranitrate
skc-file
Group of substances:
organic
Physical appearance:
colorless crystals
Empirical formula (Hill's system for organic substances):
C
5
H
8
N
4
O
1
2
Structural formula as text:
C(CH2ONO2)4
Molar/atomic mass: 316.25
Melting point (°C):
141
Solubility (g/100 g of solvent):
acetone
: 24.84 (20°C) [
Ref.
]
acetone
: 58.76 (50°C) [
Ref.
]
benzene
: 0.15 (0°C) [
Ref.
]
benzene
: 0.3 (20°C) [
Ref.
]
diethyl ether
: 0.2 (0°C) [
Ref.
]
diethyl ether
: 0.249 (20°C) [
Ref.
]
diethyl ether
: 0.431 (34.7°C) [
Ref.
]
dimethylformamide
: 70 (100°C) [
Ref.
]
ethanol
: 0.07 (0°C) [
Ref.
]
ethanol
: 0.195 (20°C) [
Ref.
]
ethanol
: 0.415 (40°C) [
Ref.
]
ethanol
: 3.795 (78.4°C) [
Ref.
]
ethyl acetate
: 10.6 (20°C) [
Ref.
]
ethyl acetate
: 14.06 (30°C) [
Ref.
]
ethyl acetate
: 18.5 (40°C) [
Ref.
]
ethyl acetate
: 24.19 (50°C) [
Ref.
]
methanol
: 0.19 (0°C) [
Ref.
]
methanol
: 0.455 (20°C) [
Ref.
]
methanol
: 2.6 (60°C) [
Ref.
]
toluene
: 0.15 (0°C) [
Ref.
]
toluene
: 0.22 (20°C) [
Ref.
]
water
: 0.0002 (20°C) [
Ref.
]
Numerical data:
Heat of Explosion (kJ/kg): 5756
Detonation velocity (m/s): 8350
Density:
1.77 (20°C, g/cm
3
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-541.65 (s)
Autoignition temperature (°C):
200
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-387 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
614.7 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
294.8 (g)
References:
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 151
Беликов В.Г. Учебное пособие по фармацевтической химии. - М.: Медицина, 1979. - pp. 138 [Russian]
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.3. - Л.: Химия, 1976. - pp. 126 [Russian]
Орлова Е.Ю. Химия и технология бризантных взрывчатых веществ. - Л.: Химия, 1981. - pp. 282 [Russian]
Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 1136, 1209-1210, 1273, 1322, 1331, 1374-1375 [Russian]
Химическая энциклопедия. - Т. 4. - М.: Советская энциклопедия, 1995. - pp. 556 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru