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Properties of substance:
ammonium hexachloroplatinate(IV)
Group of substances:
inorganic
Physical appearance:
yellow cubic crystals
Empirical formula (Hill's system for organic substances):
H
8
Cl
6
N
2
Pt
Structural formula as text:
(NH4)2[PtCl6]
Molar/atomic mass: 443.87
Decomposition temperature (°C):
215
Solubility (g/100 g of solvent):
diethyl ether
: insoluble [
Ref.
]
ethanol 95%
: 0.0037 (18°C) [
Ref.
]
water
: 0.7 (15°C) [
Ref.
]
water
: 1.25 (100°C) [
Ref.
]
Multicomponent solubility (in wt%):
water 99.012%, ammonium chloride 0.92%, ammonium hexachloroplatinate(IV) 0.068%, 25 °C [
Ref.
]
water 85.124%, ammonium chloride 14.85%, ammonium hexachloroplatinate(IV) 0.026%, 25 °C [
Ref.
]
water 73.6328%, ammonium chloride 26.36%, ammonium hexachloroplatinate(IV) 0.0082%, 25 °C [
Ref.
]
Density:
3.07 (20°C, g/cm
3
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-984.1 (s)
LD
50
(mg/kg):
195 (rats, oral)
References:
Dean J.A. Lange's handbook of chemistry. - 1999. - pp. 3.15
Journal of Chemical Thermodynamics. - 1990. - Vol. 22, No. 11. - pp. 1097-1105 [DOI:
10.1016/0021-9614(90)90158-M
]
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 232
Perry D.L. Handbook of Inorganic Compounds. - 2nd ed. - CRC Press, 2011. - pp. 24
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 1424-1425
Ефимов А.И. и др. Свойства неорганических соединений. Справочник. - Л.: Химия, 1983. - pp. 100-101 [Russian]
Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 407 [Russian]
Неорганическая химия. – Под ред. Третьякова Ю.Д., Т.3, Кн.2. - М.: Академия, 2007. - pp. 136 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 223-224 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 42 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru