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Properties of substance:

lithium bromide

Group of substances:

inorganic

Physical appearance:

colorless cubic crystals

Empirical formula (Hill's system for organic substances):

BrLi

Structural formula as text:

LiBr

Molar/atomic mass: 86.85

Melting point (°C):

549

Boiling point (°C):

1310

Solubility (g/100 g of solvent):

acetone: 18.2 (20°C) [Ref.]
acetone: 34.6 (50°C) [Ref.]
acetone: 39.7 (60°C) [Ref.]
acetonitrile: 8.28 (18°C) [Ref.]
acetonitrile: 8.81 (25°C) [Ref.]
amyl alcohol: soluble [Ref.]
benzaldehyde: 13.03 (25°C) [Ref.]
bromine liquid: 0.005 (25°C) [Ref.]
diethyl ether: soluble [Ref.]
ethanol abs.: 32.61 (0°C) [Ref.]
ethanol abs.: 36.02 (10°C) [Ref.]
ethanol abs.: 70 (13.2°C) [Ref.]
ethanol abs.: 70.2 (15°C) [Ref.]
ethanol abs.: 70.4 (16°C) [Ref.]
ethanol abs.: 70.8 (20°C) [Ref.]
ethanol abs.: 71.2 (23°C) [Ref.]
ethanol abs.: 71.3 (23.8°C) [Ref.]
ethanol abs.: 72.1 (25°C) [Ref.]
ethanol abs.: 72.51 (30°C) [Ref.]
ethanol abs.: 73.03 (40°C) [Ref.]
ethanol abs.: 77.52 (50°C) [Ref.]
ethanol abs.: 82.84 (60°C) [Ref.]
ethanol abs.: 89.13 (70°C) [Ref.]
ethanol abs.: 94.12 (75°C) [Ref.]
ethanol abs.: 99.1 (80°C) [Ref.]
ethyl acetate: sparingly soluble [Ref.]
ethylene glycol : 60 (14.7°C) [Ref.]
ethylenediamine: 2.41 (25°C) [Ref.]
formic acid: 82.88 (18°C) [Ref.]
formic acid: 80.9 (25°C) [Ref.]
glycerol: soluble [Ref.]
hydrazine: 37 [Ref.]
methanol: 117 (18°C) [Ref.]
methanol: 140 (25°C) [Ref.]
propylene carbonate: 21.12 (25°C) [Ref.]
pyridine: soluble [Ref.]
sulfur dioxide: 0.067 (25°C) [Ref.]
tetrahydrofuran: 43.6 (25°C) [Ref.]
water: 143 (0°C) [Ref.]
water: 147 (10°C) [Ref.]
water: 155 (16°C) [Ref.]
water: 160 (20°C) [Ref.]
water: 170 (25°C) [Ref.]
water: 211 (40°C) [Ref.]
water: 223 (60°C) [Ref.]
water: 245 (80°C) [Ref.]
water: 254 (90°C) [Ref.]
water: 266 (100°C) [Ref.]

Not numerical data:

hygroscopic

Density:

3.464 (25°C, g/cm3)

Vapour pressure (Torr):

0.1 (640°C)
1 (747°C)
10 (886°C)
100 (1076°C)

Viscosity (mPa·s):

1.52 (597°C)
1.14 (687°C)
0.92 (867°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-350.3 (s)

Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

-338.9 (s)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

66.9 (s)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

51.88 (s)

Molar enthalpy (heat) of fusion ΔfusH (kJ/mol):

12

Enthalpy (heat) of vaporization ΔvapH (kJ/mol):

148

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-157 (g)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

224.22 (g)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

33.93 (g)

LD50 (mg/kg):

1680 (rats, subcutaneous)
2353 (mice, oral)

References:

  1. Industrial and Engineering Chemistry Research. - 2010. - Vol. 49, No. 10. - pp. 4982
  2. Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 898-900
  3. Вредные химические вещества: Неорганические соединения элементов I-IV групп. Справочник. - Л.: Химия, 1988. - pp. 25 [Russian]
  4. Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 231-234 [Russian]
  5. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 76 [Russian]
  6. Редкие и рассеянные элементы. Химия и технология. - Кн. 1. - М.: Мисис, 1996. - pp. 32 [Russian]
  7. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 642-643, 738-739 [Russian]
  8. Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 108-109 [Russian]
  9. Химия и технология редких и рассеянных элементов. - Ч.1. - М.: Высшая школа, 1976. - pp. 21 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru