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Properties of substance:

μ-chlorobis[pentafluorophenylxenon(II)] hexafluoroarsenate

Group of substances:

elmentoorganic

Physical appearance:

colorless solid

Empirical formula (Hill's system for organic substances):

C12AsClF16Xe2

Structural formula as text:

(C6F5Xe)2Cl(AsF6)

Molar/atomic mass: 821.063

Decomposition temperature (°C):

100

Solubility (g/100 g of solvent):

acetonitrile: soluble [Ref.]
methylene chloride: insoluble [Ref.]

Interatomic distances and bond angles:

Interatomic distances (in pm): 284,7 (Xe(1)-Cl) [crystals]
Interatomic distances (in pm): 278,4 (Xe(2)-Cl) [crystals]
Interatomic distances (in pm): 211,1 (Xe(1)-C(1)) [crystals]
Interatomic distances (in pm): 211,6 (Xe(2)-C(7)) [crystals]
Interatomic distances (in pm): 337,2 (Xe(1)-F(13)) [crystals]
Interatomic distances (in pm): 315,8 (Xe(2)-F(15)) [crystals]
Bond angles (in degrees): 176 (C(1)-Xe(1)-Cl) [crystals]
Bond angles (in degrees): 178,8 (C(7)-Xe(2)-Cl) [crystals]
Bond angles (in degrees): 116,96 (Xe(1)-Cl-Xe(2)) [crystals]

References:

  1. Angewandte Chemie International Edition. - 1999. - Vol. 38, No. 17. - pp. 2554-2556
  2. Housecroft C.E., Sharpe A.G. Inorganic Chemistry. - 2ed. - 2005. - pp. 500
  3. Olah G.A., Prakash G.K.S., Molnar A., Sommer J. Superacid chemistry. - 2ed. - Wiley, 2009. - pp. 464
  4. Organometallics. - 2001. - Vol. 20, No. 23. - pp. 4753, 4755

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru