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Properties of substance:
potassium dihydrogen phosphate
Group of substances:
inorganic
Physical appearance:
colorless rhombic crystals
Empirical formula (Hill's system for organic substances):
H
2
KO
4
P
Structural formula as text:
KH2PO4
Molar/atomic mass: 136.09
Melting point (°C):
252.6
Solubility (g/100 g of solvent):
ethanol
: insoluble [
Ref.
]
ethylene glycol
: 0.816 (25°C) [
Ref.
]
ethylene glycol
: 0.839 (35°C) [
Ref.
]
formamide
: 1.2 (25°C) [
Ref.
]
phosphoric acid
: 11.81 (38.5°C) [
Ref.
]
water
: 14.8 (0°C) [
Ref.
]
water
: 18.3 (10°C) [
Ref.
]
water
: 22.6 (20°C) [
Ref.
]
water
: 25.1 (25°C) [
Ref.
]
water
: 28 (30°C) [
Ref.
]
water
: 33.5 (40°C) [
Ref.
]
water
: 50.1 (60°C) [
Ref.
]
water
: 70.4 (80°C) [
Ref.
]
water
: 83.5 (90°C) [
Ref.
]
Properties of solutions:
10% (wt.), solvent - water
Dynamic viscosity (mPa·s) = 1.245 (20°)
Density (g/cm
3
) = 1.0703 (20°)
Index of refraction = 1.3445 (20°)
Freezing point (°C) = -2.23
Hygroscopic:
yes
Density:
2.34 (20°C, g/cm
3
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-1568.6 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-1419.2 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
134.85 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
116.57 (s)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-1568.3 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-1415.9 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
134.9 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
116.6 (s)
References:
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 852-855
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 70 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 699 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 88-89 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru