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Properties of substance:
diboron tetrachloride
Synonyms:
tetrachlorodiborane
Group of substances:
inorganic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
B
2
Cl
4
Structural formula as text:
BCl2BCl2
Molar/atomic mass: 163.434
Melting point (°C):
-92.6
Boiling point (°C):
65.5
Decomposition temperature (°C):
0
CAS №: 13701-67-2
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-523 (l)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-464.8 (l)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
262.3 (l)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
137.7 (l)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-490.4 (g)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-460.6 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
357.4 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
95.4 (g)
References:
Bretherick's Handbook of Reactive Chemical Hazards. - 6 ed., Vol. 1. - Butterworth-Heinemann, 1999. - pp. 71-72
Holleman A.F., Wiberg E., Wiberg N. Lehrbuch der Anorganischen Chemie. - Berlin: Walter de Gruyter, 1995. - pp. 1028, 1033
Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 192 [Russian]
Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 16-17 [Russian]
Успехи химии. - 1964. - Т.33, №2. - pp. 235-250 [Russian]
Фурман А.А. Неорганические хлориды (химия и технология). - М.: Химия, 1980. - pp. 130-131 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru