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Properties of substance:
3,5-di-tert-butyl-4-hydroxytoluene
Synonyms:
BHT
butylated hydroxytoluene
Group of substances:
organic
Physical appearance:
white crystals
Empirical formula (Hill's system for organic substances):
C
1
5
H
2
4
O
Structural formula as text:
((CH3)3C)2(CH3)C6H2OH
Molar/atomic mass: 220.35
Melting point (°C):
70
Boiling point (°C):
265
Solubility (g/100 g of solvent):
1,4-dioxane
: 40.72 [
Ref.
]
1-butanol
: 44.42 [
Ref.
]
2-propanol
: soluble [
Ref.
]
acetone
: soluble [
Ref.
]
benzene
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
isopentane
: soluble [
Ref.
]
linseed oil: soluble [
Ref.
]
methanol
: soluble [
Ref.
]
methyl ethyl ketone
: soluble [
Ref.
]
methylene chloride
: 212.3 [
Ref.
]
petroleum ether: soluble [
Ref.
]
toluene
: very soluble [
Ref.
]
water
: insoluble [
Ref.
]
Density:
1.048 (g/cm
3
)
Dissociation:
pK
a
(1) = 12.33 (25°C, water)
pK
a
(1) = 17.18 (25°C, methanol)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-410 (s)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-296.9 (g)
LD
50
(mg/kg):
2450 (white rats, oral)
2000 (mice, oral)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-41
Jouyban A. Handbook of solubility data for pharmaceutacals. – CRC Press, 2010. - pp. 69, 72-73
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 430
Schlager N., Weisblatt J., Newton D.E. Chemical Compounds. - 2006. - pp. 133-136
The Merck Index 11th ed., Merck & Company, 1989. - pp. 238
Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.1. - Л.: Химия, 1976. - pp. 413-414 [Russian]
Горбунов Б.Н., Гурвич Я.А., Маслова И.П. Химия и технология стабилизаторов полимерных материалов. - М.: Химия, 1981. - pp. 205-212 [Russian]
Гурвич Я.А. Справочник молодого аппаратчика-химика. - М.: Химия, 1991. - pp. 183-184 [Russian]
Полюдек-Фабини Р., Бейрих Т. Органический анализ. - Л.: Химия, 1981. - pp. 87 [Russian]
Справочник химика. - Т. 6. - Л.: Химия, 1967. - pp. 246-247 [Russian]
Стэлл Д.Р. Таблицы давления паров индивидуальных веществ. - М.: ИИЛ, 1949. - pp. 34 [Russian]
Химическая энциклопедия. - Т. 2. - М.: Советская энциклопедия, 1990. - pp. 50 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 163 [Russian]
Шефтель В.О. Полимерные материалы: Токсические свойства. - Л.: Химия, 1982. - pp. 96-97 [Russian]
Энциклопедия полимеров. - Т. 1, А-К. - М.: Советская энциклопедия, 1972. - pp. 187 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru