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Properties of substance:
tungsten(VI) chloride
Group of substances:
inorganic
Physical appearance:
hexagonal crystals
Empirical formula (Hill's system for organic substances):
Cl
6
W
Structural formula as text:
WCl6
Molar/atomic mass: 396.57
Melting point (°C):
283
Boiling point (°C):
340
Solubility (g/100 g of solvent):
chlorine liquid
: sparingly soluble [
Ref.
]
diethyl ether
: very soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
phosphorus(V) trichloride oxide
: very soluble [
Ref.
]
water
: practically insoluble [
Ref.
]
water
: reaction (100°C) [
Ref.
]
Density:
3.52 (25°C, g/cm
3
)
Vapour pressure (Torr):
1 (154°C)
10 (198°C)
100 (256°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-598.3 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-469 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
268 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
163.7 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
8.4
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
61.5
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-498 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
418 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
143.5 (g)
LD
50
(mg/kg):
1800 (rats, oral)
1080 (mice, oral)
Critical temperature (°C):
650
Critical pressure (MPa):
5
Critical density (g/cm
3
):
0.94
References:
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 4-97
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 374-375 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 60 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru