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Properties of substance:
phosphonic acid
Group of substances:
inorganic
Physical appearance:
colorless crystals
Empirical formula (Hill's system for organic substances):
H
3
O
3
P
Structural formula as text:
(HO)2P(O)H
Molar/atomic mass: 81.996
Melting point (°C):
70.1
Decomposition temperature (°C):
200
Solubility (g/100 g of solvent):
ethanol
: soluble [
Ref.
]
water
: 309 (0°C) [
Ref.
]
water
: 694 (30°C) [
Ref.
]
Hygroscopic:
very hygroscopic
Density:
1.65 (21°C, g/cm
3
)
Dissociation:
pK
a
(1) = 1.257 (25°C, water)
pK
a
(2) = 6.7 (25°C, water)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-952.3 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
15.5
LD
50
(mg/kg):
1700 (, oral)
References:
Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 476-479 [Russian]
Краткая химическая энциклопедия. - Т. 5: Т-Я. - М.: Советская энциклопедия, 1967. - pp. 509 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 446 [Russian]
Постников Н.Н. Термическая фосфорная кислота. Химия и технология. - М.: Химия, 1970. - pp. 50-52 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 109 [Russian]
Токсикологический вестник. - 1995. - №6. - pp. 38 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru