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Properties of substance:

sodium trimethoxyborohydride

Group of substances:

inorganic

Physical appearance:

white crystals

Empirical formula (Hill's system for organic substances):

C3H10BNaO3

Structural formula as text:

NaBH(OCH3)3

Molar/atomic mass: 127.91

Melting point (°C):

230

Decomposition temperature (°C):

230

Solubility (g/100 g of solvent):

1,4-dioxane: 1.6 (25°C) [Ref.]
1,4-dioxane: 4.5 (75°C) [Ref.]
N,N-dimethylaniline: 1.4 (20°C) [Ref.]
N-methylmorpholine: 22 (20°C) [Ref.]
ammonia liquid : 5.6 (-33°C) [Ref.]
diethyl ether: insoluble [Ref.]
diglyme: 2.6 (20°C) [Ref.]
ethylenediamine: 0.2 (25°C) [Ref.]
ethylenediamine: 0.2 (75°C) [Ref.]
hexane: 7 (24°C) [Ref.]
isopropylamine: 9 (25°C) [Ref.]
monoglyme: 22 (20°C) [Ref.]
morpholine: 0.3 (24°C) [Ref.]
morpholine: 2.3 (75°C) [Ref.]
piperidine: 16 (20°C) [Ref.]
pyridine: 0.4 (24°C) [Ref.]
pyridine: 3 (75°C) [Ref.]
tetraglyme: 2.3 (20°C) [Ref.]
tetrahydrofuran: 40 (20°C) [Ref.]
triglyme: 1 (20°C) [Ref.]
water: soluble [Ref.]

References:

  1. Жигач А.Ф., Стасиневич Д.С. Химия гидридов. - Л.: Химия, 1969. - pp. 455-457 [Russian]
  2. Общая органическая химия. - Т. 6, под ред. Бартона Д. и Оллиса В.Д. - М.: Химия, 1984. - pp. 246 [Russian]
  3. Ситтиг М. Натрий, его производство, свойства и применение. - М.: ГИЛОАНТ, 1961. - pp. 208 [Russian]
  4. Хайош А. Комплексные гидриды в органической химии. - Л.: Химия, 1971. - pp. 64-65 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru