Main page (Russian)
Search in database (English)
Properties of substance:
lithium borohydride
Synonyms:
lithium tetrahydroborate
Group of substances:
inorganic
Physical appearance:
colorless rhombic crystals
Empirical formula (Hill's system for organic substances):
H
4
BLi
Structural formula as text:
LiBH4
Molar/atomic mass: 21.78
Melting point (°C):
268
Decomposition temperature (°C):
380
Solubility (g/100 g of solvent):
1,4-dioxane
: 0.06 (25°C) [
Ref.
]
ammonia liquid
: 30.4 (0°C) [
Ref.
]
diethyl ether
: 1.28 (0°C) [
Ref.
]
diethyl ether
: 1.37 (1°C) [
Ref.
]
diethyl ether
: 3 (20°C) [
Ref.
]
diethyl ether
: 4.28 (25°C) [
Ref.
]
diethyl ether
: 28.5 (38.8°C) [
Ref.
]
diglyme
: 1.79 (25°C) [
Ref.
]
dimethyl ether
: 1.6 (-45.2°C) [
Ref.
]
dimethylformamide
: 3.5 (25°C) [
Ref.
]
ethanol
: reaction 2.5 (25°C) [
Ref.
]
hydrazine
: 15.6 (25°C) [
Ref.
]
isopropylamine
: 8 (10°C) [
Ref.
]
methanol
: reaction 2.5 (25°C) [
Ref.
]
n-butylamine
: 5.2 (10°C) [
Ref.
]
tetrahydrofuran
: 15.5 (-23°C) [
Ref.
]
tetrahydrofuran
: 17.8 (0°C) [
Ref.
]
tetrahydrofuran
: 28 (25°C) [
Ref.
]
water
: 26.45 (10°C) [
Ref.
]
water
: reaction (20°C) [
Ref.
]
Density:
0.68 (20°C, g/cm
3
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-193.83 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
75.7 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
82.6 (s)
References:
Progress in inorganic chemistry. - Vol. 11. - John Wiley & Sons, 1970. - pp. 112, 121-127
Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 164 [Russian]
Ефимов А.И. и др. Свойства неорганических соединений. Справочник. - Л.: Химия, 1983. - pp. 148-149 [Russian]
Жигач А.Ф., Стасиневич Д.С. Химия гидридов. - Л.: Химия, 1969. - pp. 388-395 [Russian]
Михайлов В.А. Химия бороводородов. - М.: Наука, 1967. - pp. 229 [Russian]
Некрасов Б.В. Основы общей химии. - Т.2. - М.: Химия, 1973. - pp. 25-26 [Russian]
Общая органическая химия. - Т. 6, под ред. Бартона Д. и Оллиса В.Д. - М.: Химия, 1984. - pp. 245 [Russian]
Редкие и рассеянные элементы. Химия и технология. - Кн. 1. - М.: Мисис, 1996. - pp. 35 [Russian]
Реми Г. Курс неорганической химии. - Т.1. - М., 1963. - pp. 366-367 [Russian]
Репинская И.Б., Шварцберг М.С. Избранные методы синтеза органических соединений. - Новосибирск, 2000. - pp. 119 [Russian]
Хайош А. Комплексные гидриды в органической химии. - Л.: Химия, 1971. - pp. 48-53 [Russian]
Химическая энциклопедия. - Т. 1. - М.: Советская энциклопедия, 1988. - pp. 308 [Russian]
What information do you need?
© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru