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Properties of substance:
1,2,4-trimethylbenzene
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
9
H
1
2
Structural formula as text:
C6H3(CH3)3
Molar/atomic mass: 120.192
Melting point (°C):
-43.8
Boiling point (°C):
169.35
CAS №: 95-63-6
Solubility (g/100 g of solvent):
acetone
: soluble [
Ref.
]
benzene
: soluble [
Ref.
]
diethyl ether
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
water
: 0.0059 (25°C) [
Ref.
]
Density:
0.8758 (20°C, d
4
)
Refractive index (n
D
):
1.5048 (20°C)
Vapour pressure (Torr):
1 (14.8°C)
10 (51.7°C)
40 (80.5°C)
100 (103.4°C)
400 (145.6°C)
Retention indices for gas chromatography:
992,8 (phase - DB-5, temperature-programmed conditions, 6 K/min)
Viscosity (mPa·s):
0.894 (15°C)
0.73 (30°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-13.94 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
396.62 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
155.33 (g)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
12.35
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
39.57
LD
50
(mg/kg):
7000 (rats, oral)
6900 (mice, oral)
Critical temperature (°C):
380.1
Critical pressure (MPa):
3.29
References:
Dean J.A. Lange's handbook of chemistry. - 1999. - pp. 5.103
Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 584
Вредные химические вещества: Углеводороды, галогенпроизводные углеводородов. Справочник. - Л.: Химия, 1990. - pp. 175 [Russian]
Соколов В.З., Харлампович Г.Д. Производство и использование ароматических углеводородов. - М.: Химия, 1980. - pp. 14 [Russian]
Справочник нефтехимика. - Т.1, под ред. Огородникова С.К. - Л.: Химия, 1978. - pp. 478-479 [Russian]
Справочник химика. - 2 изд., Т.1. - Л.-М.: Химия, 1966. - pp. 652 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 926-927 [Russian]
Химическая энциклопедия. - Т. 4. - М.: Советская энциклопедия, 1995. - pp. 133 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru