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Properties of substance:

tetrachloroethene

Synonyms:

tetrachloroethylene

Group of substances:

organic

Empirical formula (Hill's system for organic substances):

C2Cl4

Structural formula as text:

Cl2C=CCl2

Molar/atomic mass: 165.83

Melting point (°C):

-22

Boiling point (°C):

121

Solubility (g/100 g of solvent):

diethylene glycol: 12 (25°C) [Ref.]
organic solvents: miscible [Ref.]
propylene glycol: 11.7 (25°C) [Ref.]
sulfolane: 37.5 (24.4°C) [Ref.]
water: 0.0273 (0°C) [Ref.]
water: 0.0286 (20°C) [Ref.]
water: 0.038 (80°C) [Ref.]

Density:

1.688 (-20°C, g/cm3)
1.631 (15°C, g/cm3)
1.625 (20°C, g/cm3)
1.606 (30°C, g/cm3)
1.551 (60°C, g/cm3)
1.484 (100°C, g/cm3)
1.449 (120°C, g/cm3)

Refractive index (nD):

1.5044 (20°C)

Vapour pressure (Torr):

4.91 (0°C)
7.87 (10°C)
13.96 (20°C)
20 (26.3°C)
39.3 (40°C)
93.2 (60°C)
207 (80°C)
400 (100°C)
725 (120°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-11 (g)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-50.6 (l)

Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

3 (l)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

266.9 (l)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

143.4 (l)

Critical temperature (°C):

340

Critical pressure (MPa):

4.49

Critical density (g/cm3):

0.573

References:

  1. CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-21, 8-117
  2. Journal of Physical and Chemical Reference Data. - 1999. - Vol. 28, No. 2. - pp. 411-432
  3. Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 43
  4. Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.1. - Л.: Химия, 1976. - pp. 231-233 [Russian]
  5. Промышленные хлорорганические продукты: Справочник. - М.: Химия, 1978. - pp. 187-196 [Russian]
  6. Успехи химии. - 1983. - Т.52, №5. - pp. 756 [Russian]
  7. Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 435-436 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru