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Properties of substance:
1,1-dichloroethene
Synonyms:
vinylidene chloride
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
2
H
2
Cl
2
Structural formula as text:
CH2=CCl2
Molar/atomic mass: 96.943
Melting point (°C):
-122.5
Boiling point (°C):
31.7
CAS №: 75-35-4
Solubility (g/100 g of solvent):
ammonia liquid
: miscible [
Ref.
]
water
: 0.2245 (25°C) [
Ref.
]
Density:
1.25 (15°C, d
4
)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
2.8 (g)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
25.4 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
289 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
67.1 (g)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-23.9 (l)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
24.1 (l)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
201.5 (l)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
111.3 (l)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-21
Flick E.W. Industrial solvent handbook. - 5ed. - 1998. - pp. 147-148
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 21
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - 2-е изд. - Л.: Химия, 1978. - pp. 139 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 1140-1141 [Russian]
Термодинамические свойства индивидуальных веществ. - Т.2, Кн.2. - М.: Наука, 1979. - pp. 111 [Russian]
Термодинамические свойства индивидуальных веществ. – 3-е изд. – Т.2, Кн.1. - М.: Наука, 1979. - pp. 94, 118-119 [Russian]
Успехи химии. - 1983. - Т.52, №5. - pp. 756 [Russian]
Химическая энциклопедия. - Т. 1. - М.: Советская энциклопедия, 1988. - pp. 370 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru